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  • 专利说明
  • 权利要求
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    • 专利摘要:
    The invention relates to a process for catalytic reforming of a naphtha hydrocarbon feedstock employing a plurality of reaction zones in series, said reaction zones containing a reforming catalyst bed, comprising the following steps: hydrocarbon heated with hydrogen through the reaction zones to convert paraffinic and naphthenic compounds into aromatic compounds, the effluent produced by each reaction zone except for the last reaction zone being heated before being introduced into the reaction zone next; • a reformate is withdrawn from the last reaction zone. The first reaction zone is operated under the following conditions: an average temperature of between 470 and 570 ° C .; A pressure of between 0.3 and 1.5 MPa; A ratio (mass flow rate of charge / mass of catalyst) of between 50 and 200 h -1; The molar ratio H2 / hydrocarbons of between 0.8 and 8; A quantity of catalyst of between 1 and 5% by weight of the total quantity of catalyst used.
    公开号:FR3024460A1
    申请号:FR1457315
    申请日:2014-07-29
    公开日:2016-02-05
    发明作者:Alexandre Pagot；Eric Lemaire；Heloise Dreux
    申请人:IFP Energies Nouvelles IFPEN；
    IPC主号:
    专利说明:

    [0001] The present invention relates to a process for converting a hydrocarbon feedstock of the naphtha type and in particular a catalytic reforming process for converting paraffinic compounds and / or naphthenes of the naphtha feedstock into aromatic compounds.
    [0002] STATE OF THE ART The reforming (or catalytic reforming) of hydrocarbon cuts of the naphtha type is well known in the field of refining. This reaction produces high octane fuel bases and / or aromatic cuts for petrochemicals from these hydrocarbon cuts while providing the refinery with the necessary hydrogen for other operations. The catalytic reforming process involves contacting the hydrocarbon fraction containing paraffinic compounds with naphthenes with hydrogen and a reforming catalyst, for example with platinum, and converting paraffinic compounds and naphthenes to aromatic compounds. with an associated production of hydrogen. Since the reactions involved in the reforming process (isomerization, dehydrogenation and dehydrocyclization reactions) are endothermic, it is necessary to heat the effluent withdrawn from a reactor before sending it to the next reactor.
    [0003] Over time, the reforming catalyst deactivates due to the deposition of coke on its active sites. Therefore, in order to maintain an acceptable productivity of the reforming unit, it is necessary to regenerate the catalyst in order to eliminate the deposit and thus restore its activity. There are various types of reforming processes. The first type relates to so-called "non-regenerative" processes, the catalyst remains in service for long periods but its activity decreases over time, which makes it necessary to raise the temperature of the reactors gradually and thus to have a variable selectivity during the cycle. procedure. The reactors are necessarily all turned off, which completely interrupts the production of the refinery, to regenerate the catalyst before another cycle of production.
    [0004] According to another so-called "semi-regenerative" catalytic reforming process, the catalyst is regenerated frequently in the case where several reactors are used which contain the catalyst in a fixed bed. One of the reactors is in regeneration while the other reactors are in service; it then replaces one of the reactors in service when the catalyst of the latter must be regenerated, and in this way all the reactors are alternately put out of service for regeneration, then, again, in service without the operation of the reactor. unit is interrupted. Finally there is the so-called "continuous catalyst regeneration" (CCR) reforming process which implies that the reaction is carried out in a reactor in which the catalyst continuously flows up and down. and the regeneration is continuous in an auxiliary reactor, the catalyst being recycled to the main reactor so as not to interrupt the reaction. Reference can be made to document FR 2 160 269, which discloses a catalytic reforming process with continuous regeneration of the catalyst involving several reactors with moving radial beds in series and a dedicated regenerator. According to the method FR 2 160 269, the hydrocarbon fraction in mixture with hydrogen is treated successively in each of the reactors in series while the catalyst passes continuously in all the reactors. The catalyst recovered at the outlet of the final reactor is sent regeneratively into the regenerator at the outlet of which the regenerated catalyst is reintroduced progressively into the first reforming reactor. Due to the endothermicity of the reactions involved, it is necessary to heat the effluent of a reactor before it enters the next reactor in order to maintain a sufficiently high average temperature for the conversion reactions to take place. In the state of the art, document FR 1 488 964 is known which teaches a catalytic reforming process using at least three reactors in series with intermediate reheating of the effluents and in which the last reactor comprises approximately 55% of the total weight of catalyst. while the preceding reactors share substantially the rest of the catalyst. This document proposes in particular to put at least 10% of the total weight of catalyst in the first reactor.
    [0005] An object of the invention is to propose a reforming process involving several reactors in series and for which the distribution of the catalyst in the reactors is optimized in order to maintain an optimum average temperature in all the catalytic beds to favor the reactions. reforming.
    [0006] SUMMARY OF THE INVENTION The invention thus relates to a process for catalytic reforming of a naphtha hydrocarbon feedstock employing a plurality of reaction zones in series, said reaction zones containing a reforming catalyst bed. The process comprises the following steps: - the heated hydrocarbon feedstock is sent with hydrogen through the reaction zones to convert paraffinic and naphthenic compounds to aromatic compounds, the effluent produced by each reaction zone except the last reaction zone being heated before being introduced into the next reaction zone; a reformate is withdrawn from the last reaction zone. The first reaction zone is operated under the following conditions: an average temperature of between 470 and 570 ° C .; a pressure of between 0.3 and 1.5 MPa; a ratio (mass flow rate of charge / mass of catalyst) of between 50 and 200 h -1; the molar ratio H 2 / hydrocarbons of between 0.8 and 8; a quantity of catalyst of between 1 and 5% by weight of the total amount of catalyst used. By limiting the amount of catalyst in the first reaction zone, it also limits the phenomenon of endothermicity, and therefore the temperature drop in this zone, which subsequently makes it possible to control the temperature drops experienced in the subsequent catalytic reaction zones. In addition, the use of the catalyst in this first zone is optimized by reducing the amount of catalyst poorly or little used. By better control of endothermicity in the different reaction zones, the activity of the catalyst which is directly related to the average temperature in the reaction zones is also improved. Thus with iso-amount of catalyst implemented, the method according to the invention has a better yield of reformate (C5 +) product. The process according to the invention is carried out with a total ratio (mass flow rate of charge / total mass of catalyst) of between 1 and 10 h -1 and preferably of between 1.5 and 5 h -1. Preferably, the process according to the invention uses at least four reaction zones. In a very preferred manner, the process uses five reaction zones.
    [0007] According to one embodiment, the reaction zones are in a moving bed of catalyst. According to a preferred embodiment, the process uses the so-called "continuous catalyst regeneration" technology using mobile catalyst beds in the reaction zones. In this embodiment, the reformate and the catalyst are then withdrawn separately from the last reaction zone, then the catalyst coming from the last reaction zone is sent into a regenerator and finally at least a portion of the regenerated regenerator catalyst is transferred to the regenerator. the first reaction zone. According to the so-called "moving catalyst bed" embodiment, the reaction zones are arranged respectively in reactors arranged side by side. Alternatively, the reaction zones are arranged in a vertical stack in a reactor so that the catalyst flows by gravity from one reaction zone to the next. According to another alternative embodiment to the "moving catalyst bed", the reaction zones comprise a fixed bed of catalyst. For example, the reaction zones are arranged respectively in reactors arranged side by side or are arranged in a vertical stack in a reactor. Preferably, the last reaction zone contains at least 30% by weight of the total amount of catalyst. According to a particular embodiment, when the process is carried out in four reaction zones, the amount of catalyst in the second reaction zone is between 10 and 25% by weight of the total amount of catalyst, the amount of catalyst in the reaction zone is third reaction zone is between 25 and 35% by weight of the total amount of catalyst and the amount of catalyst in the fourth reaction zone is between 35 and 64% by weight of the total amount of catalyst, it being understood that the total amount of catalyst in the four reaction zones is 100% weight. According to a preferred embodiment, the process uses five reaction zones, the amount of catalyst in the second reaction zone is between 7 and 15% by weight of the total amount of catalyst, the amount of catalyst in the third reaction zone. is between 15 and 20% by weight of the total amount of catalyst, the amount of catalyst in the fourth reaction zone is between 20 and 30% by weight of the total amount of catalyst and the amount of catalyst in the fifth reaction zone is between 30% and 57% by weight of the total amount of catalyst, it being understood that the total amount of catalyst in the five reaction zones is 100% by weight Other detailed characteristics and advantages of the catalyst invention will be better understood and will become clear from reading the description given below with reference to FIG. a simplified block diagram of the method according to the invention. FIG. 1 represents a schematic diagram of the catalytic reforming process according to the invention using four reaction zones arranged respectively in four reactors arranged in series and side by side. Figure 1 further indicates that the reactors are moving catalyst bed with continuous catalyst regeneration which is conducted in a dedicated regenerator. The gaseous hydrocarbon feedstock treated by the process is generally a naphtha cut distilling at 60 to 220 ° C and containing paraffinic compounds and naphthenes. The naphtha feedstock is, for example, derived from the atmospheric distillation of crude oil or a condensate of natural gas. The process according to the invention also applies to heavy naphthas produced by a catalytic cracking unit (FCC), coking, hydrocracking or even steam cracking gasoline. With reference to FIG. 1, the hydrocarbon charge is sent via line 1 to a heating means 2 (for example an oven) and then conveyed via line 3 to a first reaction zone 4 placed in a first reactor 5. The charge which has been heated to a temperature generally between 450 and 570 ° C. is introduced at the top of the reactor 5 and leaves the bottom to be reintroduced into the top of the second reactor 6 comprising a second reaction zone 9, and thus of continued in the third and fourth reactor 7, 8 which respectively comprise a third and fourth reaction zones 10, 11. It should be noted that the path of the load has not been illustrated to lighten the figure. Furthermore, between each reactor, the charge passes through a heating means (not shown) to bring it to a temperature between 450 and 570 ° C in each reactor. As indicated in FIG. 1, the catalyst stored in a hopper 12 is introduced into a reduction reactor 13 where it undergoes a reduction step before being conveyed to the top of the first reactor 5. The catalyst flows into the first reactor 5 by gravity and comes out from the bottom. The catalyst is then sent by means of a lift via line 14 into a hopper 15 situated above the second reactor 6. The catalyst is reintroduced at the top of the second reactor 6 from which it flows by gravity. The catalyst also travels in the same way between the second reactor 6 and the third reactor 7 and then between the third reactor 7 and the fourth reactor 8. The spent catalyst recovered at the bottom of the fourth reactor 8 is then transferred via line 20 into a hopper storage tank 21 disposed above a catalyst regenerator 22. The spent catalyst flows by gravity into the regenerator 22 where it undergoes the successive stages of combustion, oxychlorination and finally calcination to restore its catalytic activity. The regenerator 22 may for example be a regenerator as described in the documents FR 2 761 909 and FR 2 992 874. Finally, part of the regenerated catalyst stored in the lower hopper 23 is returned, via the line 24, into the hopper 12. Above the first reactor 5. According to one alternative, the process according to the invention can implement fixed-bed reaction zones of catalysts, each reaction zone being included respectively in a reactor. It is also possible according to one variant to arrange the reaction zones in a vertical stack in a single reactor with the first reaction section situated at the top of said reactor so that the feedstock and the catalyst flow downwards from a reaction zone. to the next. The process according to the invention involves a plurality of reaction zones in order to carry out the aromatic conversion of the paraffinic and naphthenic compounds contained in the hydrocarbon feedstock. Since the reactions involved are endothermic, it requires the effluent leaving a reaction zone to be preheated before entering the next reaction zone. It has been found in the first reaction zone where the reaction of conversion of naphthenes to aromatics (by dehydrogenation), which is a rapid and highly endothermic reaction, takes place is a significant drop in the average temperature in the reaction zone. This drop in temperature undergone in said first reaction zone has the consequence that part of the catalyst is found to operate under non-optimal temperature conditions. In some cases, when the amount of catalyst used in the first reaction zone is greater than 10% by weight of the total amount of catalyst, part of the catalyst is then superfluously present because it does not participate in the reaction catalytic. In accordance with the invention, the first reaction zone, which may comprise either a fixed bed or a moving catalyst bed, contains between 1% and 5% by weight of catalyst relative to the total weight of catalyst used in all the zones. reaction. In the first reaction zone, the hydrocarbon feedstock is brought into contact with the catalyst and hydrogen under the following operating conditions: an average input temperature in the reaction zone of between 470 and 570 ° C .; a pressure of between 0.3 and 1.5 MPa; a ratio of the mass flow rate of the feedstock to the mass of catalyst of between 50 and 200 h -1; a molar ratio H 2 / hydrocarbons of between 0.8 and 8. According to the invention and when the process involves four reaction zones arranged in series, the effluent obtained at the outlet of the first reaction zone is sent, after passing through. in a heating means, with hydrogen in the second reaction zone which includes a catalyst bed (mobile or stationary) which can comprise between 10 and 25% by weight of catalyst relative to the total weight of catalyst used in the reaction zone. set of reaction zones. The second reaction zone is operated under the following conditions: an average input temperature in the reaction zone of between 470 and 570 ° C .; A pressure of between 0.3 and 1.5 MPa; The effluent from the second reaction zone is subsequently treated in a third reaction zone after passing through a heating means where it is brought into contact with hydrogen and the catalyst bed. According to the invention, the catalytic bed of the third reaction zone can comprise between 25 and 35% by weight of catalyst relative to the total weight of catalyst used in all the reaction zones. The third reaction zone is operated under the following conditions: an average input temperature in the reaction zone of between 470 and 570 ° C .; a pressure of between 0.3 and 1.5 MPa; Finally, the effluent from the third reaction zone is sent after heating with hydrogen in the fourth reaction zone including a catalyst bed comprising at least 35% by weight and preferably between 35 and 65% by weight of catalyst relative to the weight. total of catalyst used in all the reaction zones. This reaction step is generally carried out under the following conditions: an average input temperature in the reaction zone of between 470 and 570 ° C .; a pressure of between 0.3 and 1.5 MPa. According to a very preferred embodiment, the process involves five reaction zones arranged in series with the following catalyst distributions: 1 st reaction zone: 1-5% by weight of the total amount of catalyst used; 2nd reaction zone; 7 - 15% by weight of the total amount of catalyst used - 3rd reaction zone: 15 - 20% by weight of the total amount of catalyst used - 4th reaction zone: 20 - 30% by weight of the total amount of catalyst implementation - 5th reaction zone: 30 - 57% by weight of the total amount of catalyst used The reaction zones (from the 2nd to the 5th) are further operated under the following conditions: in the reaction zone between 470 and 570 ° C; a pressure of between 0.3 and 1.5 MPa. In addition, the process according to the invention is carried out with a global ratio (mass flow rate of hydrocarbon feedstock / total mass of catalyst used) of between 1 and 10 h -1, preferably between 1.5 and 5 h -1. 1.
    [0008] The reforming catalyst used in the process according to the invention generally comprises a porous support, platinum and a halogen. Preferably the catalyst comprises platinum and chlorine with an alumina support. The catalyst may further comprise other elements (promoters) which are selected from: Re, Sn, In, P, Ge, Ga, Bi, B, Ir, rare earths, or any combination thereof. In general, the platinum content is between 0.01 and 5% by weight of platinum relative to the total weight of catalyst and preferably between 0.1 and 1% by weight of platinum based on the total weight of catalyst. Although the halogen may be selected from chlorine, bromine, fluorine and iodine, chlorine is preferable to provide the necessary acidity to the catalyst. The halogen represents, expressed in element, between 0.5 and 1.5% by weight relative to the total weight of catalyst. Preferably, the process according to the invention is carried out in side-by-side series reactors which use a so-called "moving bed" flow of the catalyst, ie a slow gravitational flow of the particles. of catalyst. Generally in this type of reactor, the particles are confined in an annular enclosure which is limited either by the reactor wall or by a cylindrical envelope consisting of a plurality of filtration ducts (or scallops according to the English terminology) and a duct interior corresponding to the central collector for the collection of effluents. More precisely in this type of so-called "radial moving bed" reactor, the feedstock is generally introduced through the outer periphery of the annular catalyst bed and passes therethrough substantially perpendicular to the vertical direction of the reactor and the reaction effluents are recovered. in the central collector. Concomitantly, the catalyst particles which descend gravitarily along the annular bed are removed from the reactor by means of conduits (or catalyst withdrawal leg). Although the process according to the invention is preferably carried out using radial flow mobile bed reactors, it is quite possible to use fixed bed catalyst reactors. EXAMPLES Example 1 (not in accordance with the invention) In Example 1, a hydrocarbon feedstock is treated in four reaction zones arranged in series in four reactors, the first reaction zone containing a quantity of catalyst greater than 5%. weight of the total quantity of catalyst used. The distribution of the catalyst in the reactors is as follows: 10 ° / 0/20 ° / 0/30% / 40% by weight relative to the total weight of catalyst. The total amount of catalyst is 100 tons. Table 1 gives the composition of the hydrocarbon feedstock (initial boiling point 100 ° C, boiling point 165 ° C): Composition Paraffins 54 feedstock (wt%) olefins 0 naphthenes 33 aromatics 13 RON 47 Flow rate ( t / h) 200 Table 1 The overall ratio (mass flow rate / total mass of catalyst), ie (200 tonnes of hydrocarbon feed per hour / 100 tonnes of catalyst), is 2h-1. The catalyst used in the reactors comprises a chlorinated alumina support, platinum and is promoted with tin.
    [0009] The charge heated to 520 ° C. is thus treated successively in the four reactors with an intermediate heating of the effluent at 520 ° C. before it is introduced into the next reaction zone. The operating conditions in the four reaction zones are given in Table 2. These conditions were chosen to produce a reformate recovered at the outlet of the fourth reactor, the RON (Research Octane Number in English terminology) being less than 102. 25 Reactor 1 Reactor 2 Reactor 3 Reactor 4 Inlet temperature 520 520 520 520 from reactor (° C) Pressure (MPa) 0.69 0.65 0.60 0.55 Mass Flow Rate 20.0 10 , 0 6.7 5.0 filler / mass of catalyst (h-1) Molar ratio 1.5 - - - H2 / hydrocarbons (mol / mol) Table 2 Example 2 (not in accordance with the invention) Example 2 is similar to Example 1 except that the hydrocarbon feed is treated in five reactors arranged in series with a following catalyst distribution: 10 ° A / 10 ° A / 10 ° A / 20 ° A / 30% by weight relative to the total weight of catalyst. The total amount of catalyst is 100 tonnes to treat a hydrocarbon feed rate of 200 t / h. The overall ratio (mass flow rate / total catalyst mass), ie (200 tonnes of hydrocarbon feed per hour / 100 tonnes of catalyst), is 211-1. The molar ratio H 2 / hydrocarbons (mol / mol) is set at 1.5 in the first reactor. As in Example 1, the feed and effluent of a reaction zone are heated to 520 ° C before entering the next reaction zone. Table 3 gives the operating conditions used in the five reactors. Reactor 1 Reactor 2 Reactor 3 Reactor 4 Reactor 5 Inlet temperature 520 520 520 520 520 from the reactor (° C) Pressure (MPa) 0.74 0.69 0.65 0.60 0.55 Mass Flow Rate 20.0 20 , 20.0 10 6.7 filler / mass of catalyst (h-1) Molar ratio 1.5 - - - H2 / hydrocarbons (mol / mol) Table 3 Example 3 (according to the invention) Example 3 corresponds to Example 1 except that the hydrocarbon feed is treated in five reactors arranged in series with a distribution of the following catalyst: 2 ° A / 10 ° A / 20 ° A / 30 ° A / 38% by weight relative to the total weight of catalyst. The total amount of catalyst is 100 tonnes to treat a hydrocarbon feed rate of 200 t / h. The overall ratio (mass flow rate / total catalyst mass), ie (200 tonnes of hydrocarbon feed per hour / 100 tonnes of catalyst), is 211-1. As in Example 1, the feed and effluent of a reaction zone are heated to 520 ° C before entering the next reaction zone.
    [0010] The operating conditions in the reaction zones of the reactors are summarized in Table 4 below: Reactor 1 Reactor 2 Reactor 3 Reactor 4 Reactor 5 Temperature in 520 520 520 520 520 reactor inlet (° C) Pressure (MPa) 0.74 0, 69 0.65 0.60 0.55 Flow ratio 100.0 20.0 10.0 6.7 5.26 mass load / mass of catalyst (1-1-1) Molar ratio 1.5 - - - - H2 / hydrocarbons (mol / mol) Table 4 Table 5 gives the average temperature of the catalytic beds of the different reactors. Example 1 Example 2 Example 3 (not in accordance with the invention) (not according to the invention) (according to the invention) Reactor 1 414 414 421 Reactor 2 452 463 460 Reactor 3 469 480 470 Reactor 4 486 481 483 Reactor 5 - 496 498 Table 5 Thus by implementing the process according to the invention, that is to say by limiting the amount of catalyst in the first reaction zone to a value of between 1 and 5% by weight relative to total weight of catalyst, the endothermy is limited in this reaction zone and ultimately the overall endotherm of the reforming unit.
    [0011] Since the activity of the catalyst is a function of the average temperature in the catalyst bed, limiting the temperature drop therefore improves the yield of compounds in aromatics, as shown in Table 6. Example 1 Example 2 Example 3 ( non-conforming to (not in accordance with (according to the invention) the invention) the invention) mass flow rate of mass / mass 2 2 2 total catalyst (h-1) yield in reformate (C5 +) 91.8 90 , 9 90.7 (`) / 0 wt.) Yield of aromatics 72.1 75.0 75.3 (`) / 0 wt.) RON of the reformate 102 104.2 104.4 Table 6 This increase in temperature in the beds Catalysts greatly affect the activity of the catalyst. For the same amount of catalyst as illustrated above, the gain in production of aromatics allows an improvement in RON of 2.4 points in the case of Example 3 compared to Example 1 and an improvement of 0, 2 point of RON in the case of Example 3 with respect to Example 2. Example 4 (according to the invention) Example 4 corresponds to Example 3 with the same catalyst distributions in the five reactors. In contrast, the total amount of catalyst was set at 42 tonnes at a feed rate of 200 t / h in order to obtain an RON of the reformate (C5 ±) of at least 102. Table 7 compares the reformate yields. (C5 ±) and aromatics of Examples 1 and 4.
    [0012] EXAMPLE 1 Example 4 (not in accordance with the invention) (according to the invention) Charge rate / quantity 2 4.8 total of catalyst (h-1) Yield in reformate 91.8 92.2 (C5 +) (` Yield of aromatics 72.1 72.6 (wt / wt) RON of reformate 102 Table 7 The process according to the invention makes it possible to produce a reformate with a high RON index by using a quantity less catalyst. The 0.4% by weight increase in the reformate yield of the unit is probably related to a lower hydrocracking rate due to the use of a smaller amount of catalyst. It is also noted that the yield of aromatics of Example 4 is improved over that of Example 1 (not in accordance with the invention). 10
    权利要求:
    Claims (15)
    [0001]
    REVENDICATIONS1. A process for the catalytic reforming of a naphtha hydrocarbon feedstock employing a plurality of reaction zones in series, said reaction zones containing a reforming catalyst bed, the process comprising the following steps: a) the hydrocarbon feed is sent heated with hydrogen through the reaction zones to convert paraffinic and naphthenic compounds into aromatic compounds, the effluent produced by each reaction zone except for the last reaction zone being heated before being introduced into the next reaction zone; b) a reformate is withdrawn from the last reaction zone, characterized in that in the first reaction zone, operation is carried out under the following conditions: a mean temperature of between 470 and 570 ° C .; a pressure of between 0.3 and 1.5 MPa; a ratio (mass flow rate of charge / mass of catalyst) of between 50 and 200 h -1; an H 2 / hydrocarbon molar ratio of between 0.8 and 8; a quantity of catalyst of between 1 and 5% by weight of the total amount of catalyst used.
    [0002]
    2. Method according to claim 1, wherein the overall ratio (mass flow rate of charge / total mass of catalyst) is between 1 and 10 h-1.
    [0003]
    3. Method according to claim 2, wherein the overall ratio (mass flow rate of charge / total mass of catalyst) is between 1.5 and 5 h-1.
    [0004]
    4. Method according to one of the preceding claims, wherein the other reaction zones are operated at: - an average temperature between 470 and 570 ° C; a pressure of between 0.3 and 1.5 MPa;
    [0005]
    5. Method according to one of the preceding claims, comprising at least four reaction zones in series.
    [0006]
    6. Method according to one of the preceding claims, wherein the reaction zones are moving beds of catalyst.
    [0007]
    7. Process according to claim 6, in which: the reformate and the catalyst are withdrawn separately from the last reaction zone; the catalyst from the last reaction zone is sent into a regenerator; and - at least a portion of the regenerated catalyst from the regenerator is transferred to the first reaction zone.
    [0008]
    8. Method according to one of the preceding claims, wherein the reaction zones are arranged respectively in reactors arranged coast-to-coast.
    [0009]
    9. Method according to one of claims 1 to 7, wherein the reaction zones are arranged in a vertical stack in a reactor so that the catalyst flows by gravity from one reaction zone in the next.
    [0010]
    10. Process according to one of claims 1 to 5, wherein the reaction zones comprise a fixed bed of catalyst.
    [0011]
    11. The method of claim 10, wherein the reaction zones are arranged respectively in reactors arranged side by side.
    [0012]
    12. The method of claim 10, wherein the reaction zones are arranged in a vertical stack in a reactor.
    [0013]
    The process according to any one of the preceding claims, wherein the last reaction zone contains at least 30% by weight of the total amount of catalyst.
    [0014]
    14. Process according to one of the preceding claims using four reaction zones and in which the amount of catalyst in the second reaction zone is between 10 and 25% by weight of the total amount of catalyst, the amount of catalyst in the third zone. The reaction zone is between 25 and 35% by weight of the total amount of catalyst and the amount of catalyst in the fourth reaction zone is between 35 and 64% by weight of the total amount of catalyst.
    [0015]
    15. Method according to one of claims 1 to 13 implementing five reaction zones and wherein the amount of catalyst in the second reaction zone is between 7 and 15% by weight of the total amount of catalyst, the amount of catalyst in the third reaction zone is between 15 and 20% by weight of the total amount of catalyst, the amount of catalyst in the fourth reaction zone is between 20 and 30% by weight of the total amount of catalyst and the amount of catalyst in the fifth The reaction zone is between 30 and 57% by weight of the total amount of catalyst. 30 35 40
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    同族专利:
    公开号 | 公开日
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    CN105316029B|2019-08-06|
    US20160032199A1|2016-02-04|
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    FR1457315A|FR3024460B1|2014-07-29|2014-07-29|OPTIMIZED DISTRIBUTION REFORMING PROCESS OF THE CATALYST.|FR1457315A| FR3024460B1|2014-07-29|2014-07-29|OPTIMIZED DISTRIBUTION REFORMING PROCESS OF THE CATALYST.|
    US14/810,990| US9657235B2|2014-07-29|2015-07-28|Reforming process with optimized distribution of the catalyst|
    CN201510453199.8A| CN105316029B|2014-07-29|2015-07-29|The reforming method of catalyst distribution with optimization|
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